Copper II Sulfide
Copper ii sulfide or cupric sulfide represented by the chemical formula CuS that bears the IUPAC name sulfanylidenecopper [1] is a black powder or lumps that is soluble in nitric acid but insoluble in water [3]. It occurs as the mineral covellite and is an ionic compound [3, 4]. It is stable in air when it is dry but gets oxidized to copper sulfate by moisture in the air [1].
Copper II Sulfide Identification |
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CAS Number | 1317-40-4 [1] |
PubChem CID | 14831 [1] |
ChemSpider ID | 145403 [2] |
EC Number | 215-271-2 [1] |
Composition and Synthesis
Copper ii sulfide can be prepared by a reaction between molten sulfur and copper that is later followed by boiling in sodium hydroxide [1].
Cu + S = CuS
Properties and Characteristics of Copper 2 Sulfide
General Properties |
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Molar mass/molecular weight | 95.606 g/mol [1] | |
Physical Properties |
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Color/appearance | Black powder [3] | |
Melting point/freezing point | 220°C, 428°F (decomposes) [3] | |
Boiling point | N/A [3] | |
Density | 4.6 g ml-1 at 25°C [3] | |
State of matter at room temperature (normal phase) | Solid [3] | |
Refractive index | 1.45 [1] | |
Chemical Properties |
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Solubility in water | N/A [1] | |
Atomic Properties |
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Crystal structure | Hexagonal [1] |
Prominent Reactions of CuS
Copper ii sulfide reacts with oxygen at a temperature of 300-500°C to form copper oxide and sulfur dioxide [7].
2CuS + 3O2 = 2CuO + 2SO2
Cupric Sulfide Uses
- In the preparation of mixed catalysts [3].
- In developing aniline black dye for textile printing [3].
- In antifouling paints [3].
- In photo optic applications and as a semiconductor [6].
Is It Dangerous
Cupric sulfide is toxic if ingested. Contact with eyes and skin and inhalation should be avoided since it may cause irritation. It has a long lasting harmful effect on aquatic life [1, 3, 5]. Under fire conditions, it decomposes to produce hazardous copper oxides and sulfur oxides [8].
- References
- Copper (II) Sulfide – Pubchem.ncbi.nlm.nih.gov
- Copper (II) Sulfide – Chemspider.com
- Copper (II) Sulfide – Chemicalbook.com
- Ionic bond examples – Examples.yourdictionary.com
- Copper Sulfide CuS – Espimetals.com
- Copper Sulfide – Americanelements.com
- Copper sulfide react with oxygen – Chemiday.com
- Material Safety Data Sheet – Chembk.com